borohydride相关论文
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Anodic oxidation of formic acid on PdAuIr/C-Sb2 O5·SnO2 electrocatalysts prepared by borohydride red
PdAuIr/C-Sb2 O5·SnO2 electrocatalysts with Pd:Au:Ir molar ratios of 90:5:5, 70:20:10 and 50:45:5 were prepared by boroh......
AB5-type Hydrogen Storage Alloy Modified with Ti/Zr Used as Anodic Materials in Borohydride Fuel Cel
该文从挂篮荷载计算、施工流程、支座及临时固结施工、挂篮安装及试验、合拢段施工、模板制作安装、钢筋安装、混凝土的浇筑及养生......
AB5-type Hydrogen Storage Alloy Modified with Ti/Zr Used as Anodic Materials in Borohydride Fuel Cel
Fuel cell using borohydride as the fuel has received much attention. AB5-type hydrogen storage alloy used as the anodic ......
Anodic oxidation of formic acid on PdAuIr/C-Sb2 O5 SnO2 electrocatalysts prepared by borohydride red
PdAuIr/C-Sb2 O5·SnO2 electrocatalysts with Pd:Au:Ir molar ratios of 90:5:5, 70:20:10 and 50:45:5 were prepared by boroh......
Polarization data of BH_4~- oxidation on Cu anode in alkaline solution were measured at steady state by a self-made expe......
氯型季我安盐型强碱性阴离子交换树脂711^#与硼氢化钾反应制得聚合物硼氢阴离子还原剂,树脂容量3.2mmol BH4/g。用于不同酯化合物的还原,操作简便,树脂......
以硼氢化物作为燃料电池的燃料因其高的理论电动势和比能量而引起研究者的广泛关注。理论上,BH4^-的电氧化反应为八电子反应,但实......
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Problems associated with carbon support corrosion under operating fuel cell conditions require the identification of alt......
研究了以硼氢化物作为还原剂的化学镀金溶液,通过正交实验得出了主盐、还原剂、络合剂,PH值和温度对镀速影响的关系,对正交实验结果进行......
采用机械球磨法制备银镍合金,并将其用作直接硼氢化物燃料电池(DBFC)的阳极催化剂.XRD和SEM实验表明,这种催化剂为纳米粒子集聚的微......
使用循环伏安法、电化学交流阻抗法研究了铜电极上BH4-在不同硫脲浓度时的电化学氧化行为。实验结果表明在扫描速率40 mV/s时,硫脲......
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AB5-type Hydrogen Storage Alloy Modified with Ti/Zr Used as Anodic Materials in Borohydride Fuel Cel
Fuel cell using borohydride as the fuel has received much attention. AB5-type hydrogen storage alloy used as the anodic ......
采用价廉易得的硼氢化钾代替硼氢化钠与717~#强碱性阴离子交换树脂反应,合成了硼氢化物聚合物还原试剂,本法经济、简便,所得试剂的......
文中较全面地研究了NaBH4预处理对H2O2漂白TMP浆白度与强度的影响,并提出NaBH4预处理较合理的工艺技术条件。......
THE TRANSITION METAL COMPOUNDS CATALYZED BOROHYDRIDE EXCHANGE RESIN TO REDUCE THE AROMATIC NITRO COM
Aromatic nitro compounds are reduced to correspouding amiues inethanol by borohydride exchauge resin(BER)in the presence......
Borohydride exchange resin-transition metal(Co,Ni,Cu,)compoundsystems reduced C=C double to C-C single bond in ethanol....
研究了胍基稀土硼氢化物 [Ph2NC(NCy)2]Ln(BH4)2 [Ph=C6H5, Cy=C6H11, Ln=Er(1)、Yb(2)]、 [(Me3Si)2NC(NCy)2]Ln(BH4)2 [Ln=Er(3)、 Yb(4)] 和 [(Me3S......
直接硼氢化物燃料电池(DBFC)因其高的理论电压和阳极电氧化速率而引起广泛的关注。在本研究中,建立了以碳载钴酞菁(CoPc/C)为阴极催化......
设计了一种无膜型被动式直接硼氢化物燃料电池(DBFC)堆,对由4个电池单元(电极面积为2cm2)通过后空翻式串联而成的电池堆研究表明:其开路......
Methanol oxidation in acidic and alkaline electrolytes using PtRuIn/C electrocatalysts prepared by b
PtRuIn/C electrocatalysts(20%metal loading by weight)were prepared by sodium borohydride reduction process using H 2 PtC......
The main objective of this paper was to characterize the voltammetric profiles of the Pt/C,Pt/C-ATO,Pd/C and Pd/C-ATO el......
引言 对于便携式燃料电池来说,燃料的“随载”储存尤为重要,开发使用液态燃料的直接液态进料燃料电池(DLFFC)一直是研究者们的努力方向......
Stability of borohydrides is determined by the localization of the negative charge on the boron atom.Ionic liquids(ILs) ......
采用高能球磨法制备了3NaBH4/ErF3复合储氢材料,并研究了其相结构和储氢性能.x射线衍射(XRD)显示,NaBH。和ErF,在球磨过程中未发生反应;同......
IntroductionAsamildreductant,sodiumborohydride(NaBH4)iswidelyusedinorganicsynthesistopreparealcoholsfromaldehydesandketones.C.........
It was established that application of bipolar membrane in a direct borohydride fuel cell (DBFC) with H2O2 co-generation......
PhSe-Na+ generated in situ by reduction of PhSeSePh, with sodium borohydride on reaction with N-(2-bromoethyl) phthalimi......
A Facile Route to Phosphanylborohydrides:Synthesis, Crystal Structure and Spectroscopic Properties o
A novel and simple synthetic way using NaBH4 in the mixure of H2O-THF was applied to prepare 1,2-bis(diphenylphosphinobo......
Reductive amination of aldehydes and ketones using sodium borohydride in the presence of silica chlo
A simple and convenient procedure for the preparation of amines from aldehydes and ketones with sodium borohydride activ......
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Two new hydrogen storage compounds,Na Zn(BH4)3·en and Na Zn(BH4)3·2en(en=ethylene diamine)are synthesized by a......
综述了不同聚合物载体和无机载体担载的硼氢还原剂的制备及其在有机合成中的应用。...
使用KBH4与717^#阴离子交换树脂反应,制备了聚合物支载的硼氢化试剂,并用BER对多种芳醛进行了还原。从结构上分析了取代 基对还原结果的影响,并探......